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Telluride iodide

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The telluride iodides are chemical compounds that contain both telluride ions (Te2−) and iodide ions (I−). They are in the class of mixed anion compounds or chalcogenide halides.[1]

Tellurium does not normally bond with iodine, but can form many different units with bonds to other tellurium atoms.

List

[edit]
name formula system space group unit cell volume density properties ref
Copper telluride iodide CuTeI tetrahedral I41/amd a = 17.170, c = 4.876, and Z = 16 Cu+1 ion conductor; metallic grey [2][3]
(CuI)3Cu2TeS3 P3121 [1]
gallium telluride iodide GaTeI orthorhombic band gap 2.55 [1]
Ge40.0Te5.3I8 cubic Pm3n a=10.815 Z = 1 1265.0 6.023 band gap 0.8 eV; clathrate [4]
α-Arsenic telluride iodide AsTeI monoclinic P21 a=8.965 b=4.042 c=10.341 β=90.75 Z=4 5.84 melt 281°C black [5]
β-Arsenic telluride iodide AsTeI cubic Fm3m a=5.791 Z=2 5.63 black metallic [5]
As4Te5I2 monoclinic a=14.58 b=4.00 c=12.26 β=95.0 Z=2 5.51 melt 303 °C metallic [5]
triniobium telluride heptaiodide Nb3TeI7 [1]
NbTe4I P21/c a=7.695 b=15.393 c=13.438 β=100.84 Z=8 1563.2 6.205 black metallic [6]
diniobium hexatelluride iodide Nb2Te6I P21/c a=9.197 b=13.387 c=9.651 β=112.36 1093.8 6.548 [1][7]
Nb4Te12I monoclinic C12/c1 a=21.957 b=6.147 c=19.925 β=122.40 Z=4 2270.6 5.8 black [8]
Nb4Te17I4 monoclinic C2/c a = 16.199 b = 8.128 c = 27.355 β = 110.84°, Z = 4 black metallic [9]
Mo3Tel0Il0 [1]
[Mo3Se7(TeI3)I2]I monoclinic P23/n a=10.4969 b=13.029 c=16.567 β =102.921° Z=4 2208.3 5.202 [1][10]
[Mo3Te7(TeI3)3]2(I)(TeI3) triclinic P1 a=11.2148 b=11.6550 c=16.6798 α=92.124 β=102.223 γ=117.427 Z= 1868.4 5.374 [1][10]
Palladium telluride iodide PdTeI a=7.821 c=5.659 brass yellow [11][12]
Ag23Te12I orthorhombic Pnnm honeycomb Te [1]
Ag19Te6Br5.4I1.6 orthorhombic Pnma electric conductor [1]
indium telluride iodide InTeI monoclinic P21/c [13]
Antimony telluride iodide SbTeI triclinic P1 [1]
(Sb2Te2)I[AlI4] monoclinic P21/n [1]
La2TeI2 rhombohedral R3m a = 4.5074 c = 32.528 Z = 3 metallic [1][14]
Er17.3Te24I8 Fd3m a=12.020 [15]
Ta3TeI7 hexagonal P63mc [1]
[TaTe4]4[PtI6]I2 triclinic P1 a=16.831 b=17.740 c=19.018 α=93.57 β=94.08 γ=102.09 Z=1 977.65 [16]
TaTe4I triclinic P1 a=6.679 b=7.787 c=8.581 α=112.76 β=102.60 γ=101.25 Z=2 381.8 7.118 black [6]
W2Cl12Te6I2 [17]
Gold telluride iodide AuITe monoclinic a=7.317 b=7.626 c=7.249 β=106.33 7.73 semiconductor band gap 0.9 grey melt 360°C [18]
Gold telluride diiodide AuITe2 orthorhombic Pmmb a = 4.056 Å, b = 12.579 Å, c = 4.741 Å, Z = 2 241.9 7.989 silvery white conductor melt 440°C [19]
Hg3Te2I2 greyish red [1]
Hg3Te2BrI monoclinic C2 18.376 b=9.587 c=10.575 β=100.11° [20]
Hg3TeI4 cubic F43m a=6.244 Z=(80% partial occupancy) 243.4 7.03 decompose 273°C dark ruby red [21]
Bismuth telluride iodide BiTeI P3m1 / Pnma over 3.9 GPa Weyl semimetal; under semimetal [1]
ThTe2I2 monoclinic C2/m a  = 7.642 b  = 14.336 c  = 7.727 and β = 111.27° Z = 4 [22]
[Ta7(Se2)14][U2I10]2 orthorhombic Cccm a = 21.5134 b = 22.1619 and c = 16.7834 Z=4 [23]

References

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  1. ^ a b c d e f g h i j k l m n o p Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews. 347: 23–47. doi:10.1016/j.ccr.2017.06.010.
  2. ^ Carkner, Philip M.; Haendler, Helmut M. (June 1976). "The crystal structure of copper bromide telluride". Journal of Solid State Chemistry. 18 (2): 183–189. Bibcode:1976JSSCh..18..183C. doi:10.1016/0022-4596(76)90094-3.
  3. ^ Fenner, J.; Rabenau, A. (September 1976). "Über Tellurhalogenide des Kupfers mit hoher Ionen-Teilleitfähigkeit Die Kristallstruktur von CuTeJ" [Telluride halides of copper with high ionic partial conductivity]. Zeitschrift für anorganische und allgemeine Chemie (in German). 426 (1): 7–14. doi:10.1002/zaac.19764260103. ISSN 0044-2313.
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  7. ^ Tremel, Wolfgang (March 1992). "Niobium telluride iodide, Nb2Te6I, a pseudo-two-dimensional compound with a new mode of transition-metal bonding for a dichalcogen group". Inorganic Chemistry. 31 (5): 755–760. doi:10.1021/ic00031a012. ISSN 0020-1669.
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  10. ^ a b Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10 , Mo 3 Se 7 TeI 6 , and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †". Inorganic Chemistry. 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.
  11. ^ Güler-Kılıç, Sümeyra; Kılıç, Çetin (2015-06-08). "Crystal and electronic structure of BiTeI, AuTeI, and PdTeI compounds: A dispersion-corrected density-functional study". Physical Review B. 91 (24): 245204. arXiv:1506.05687. Bibcode:2015PhRvB..91x5204G. doi:10.1103/PhysRevB.91.245204. ISSN 1098-0121. S2CID 118467913.
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  13. ^ Lange, Stefan; Nilges, Tom (May 2006). "Ag10Te4Br2: A New Silver(I) (poly)Chalcogenide Halide Solid Electrolyte". Chemistry of Materials. 18 (10): 2538–2544. doi:10.1021/cm060226m.
  14. ^ Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (December 2006). "La 2 TeI 2 : A New Layered Telluride Iodide with Unusual Electrical Properties". Inorganic Chemistry. 45 (26): 10728–10733. doi:10.1021/ic061675r. ISSN 0020-1669. PMID 17173429.
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  16. ^ Tremel, Wolfgang; Stork, Karl-Ludwig (1993-09-01). "[TaTe4]4[PtI6]I2, ein neues quaternäres Tellurid-Iodid mit Kettenstruktur / [TaTe4]4[PtI6]I2, A New Quaternary Telluride-Iodide with Chain Structure". Zeitschrift für Naturforschung B. 48 (9): 1155–1160. doi:10.1515/znb-1993-0901. ISSN 1865-7117. S2CID 93309355.
  17. ^ Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides". Angewandte Chemie International Edition in English. 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.
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  20. ^ Minets, Yu.V; Voroshilov, Yu.V; Pan’ko, V.V (March 2004). "The structures of mercury chalcogenhalogenides Hg3X2Hal2". Journal of Alloys and Compounds. 367 (1–2): 109–114. doi:10.1016/j.jallcom.2003.08.020.
  21. ^ Wiedemeier, Heribert; Hutchins, Mark A.; Grin, Yuri; Feldmann, Claus; von Schnering, Hans Georg (November 1997). "The Synthesis and Crystal Structure of Hg3TeI4". Zeitschrift für anorganische und allgemeine Chemie. 623 (11): 1843–1846. doi:10.1002/zaac.19976231129. ISSN 0044-2313.
  22. ^ Rocker, Frank; Tremel, Wolfgang (2001). "Synthesis and Structure of ThTe2I2". Zeitschrift für anorganische und allgemeine Chemie. 627 (6): 1305–1308. doi:10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J. ISSN 1521-3749.
  23. ^ Wells, Daniel M.; Ibers, James A. (March 2010). "The [U 2 I 10 ] 2- Anion: Synthesis and Structure of [Ta 7 (Se 2 ) 14 ][U 2 I 10 ] 2". Zeitschrift für anorganische und allgemeine Chemie. 636 (3–4): 440–442. doi:10.1002/zaac.200900416.
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